Help with an equation needed

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wautd
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Help with an equation needed

Post by wautd »

Because I suck in math and phyiscs. I'm sure it doesn't explain anything but since I don't know what the hell that formula means, I need to explain why

Quote in question:
Here is the entropy rate balance for a control volume:

dScv/dt = Sum(Qj/Tj) + Sum(mi*si) - Sum(me*se) + sigma_cv

This equation applies to open systems! So evolutionists are dishonest when they say the Second Law of Thermodynamics does not apply to open systems!
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Post by Kuroneko »

I assume a few derivatives were dropped, or else it doesn't make sense; in the following, an apostraphe shall represent derivative with respect to time. Q'_j is the rate of heat transfer on the boundary where the temperature is T_j, so their ratio is an entropy transfer. The next two terms involving (m')(s) is contribution of mass flow through the control volume (split into inflow and outflow for convenience, I suppose). The only thing that's missing would be entropy generation, which I guess would be the last term.

If one simply posits such a decomposition for the entropy of a control volume, then of course it also applies to open systems. But the entire trick behind this sort of argument is a very thinly veiled misdirection: the second law of thermodynamics is explicitly specifies adiabatic closed systems, stating dS/dt >= 0 for such systems. It is plainly evident that dS/dt can be negative otherwise, simply by having sufficiently negative Q' terms (i.e., we extract heat from the system, moving the entropy outside the control volume) or suitably large (m'_e)(s_e) terms (i.e., if we keep taking out mass from the control volume, we can also move the entropy elsewhere). But 'adiabatic' means Q' = 0 and 'closed' means m' = 0, so the given this equation, second law is simply that sigma_cv >= 0, i.e., the rate of entropy generation in the control volume is non-negative.

In other words, the second law of thermodynamics is really about the sigma_cv term only; it's just that for closed adiabatic systems, dS_cv/dt = sigma_cv.
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Il Saggiatore
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Post by Il Saggiatore »

Here is the entropy rate balance for a control volume:

dScv/dt = Sum(Qj/Tj) + Sum(mi*si) - Sum(me*se) + sigma_cv

This equation applies to open systems! So evolutionists are dishonest when they say the Second Law of Thermodynamics does not apply to open systems!
Yes, we know that creationists are proficient with copy&paste.

I would say that the equation makes sense: look up a book about thermodynamics of systems out of equilibrium (the name Prigogine** comes to mind).
When you do that, you can see how the second law of thermodynamics can be generalized and a phenomenological equation* as the above can be defined.

Now, if my memory is not betraying me:
dScv/dt = total rate of entropy production (or change, if you like) in the control volume cv.

Sum(Qj/Tj) = entropy change due to reversible transformations in the control volume; this the entropy as equilibrium-state parameter we know and love from equilibrium thermodynamics.

Sum(mi*si) = rate of incoming entropy, due to processes between the control volume and the environment.
Sum(me*se) = rate of outgoing entropy, due - again - to processes between the control volume and the environment.

sigma_cv = rate of entropy production due to irreversible transformations in the control volume.

If creationists actually understood the equation they copied (or at least knew some algebra), they would realize that this open system can reduce its entropy, that is, dScv/dt can be negative as long as Sum(me*se) is large enough or Sum(Qj/Tj) is negative. This is one of the reasons why an open system out of equilibrium can show self-organization... such as life.

The creationist shot himself in the foot, because that equation exactly refutes the traditional creationist argument that the second law of thermodynamics would not allow the development of life.
Since he decided to go into out-of-equilibrium thermodynamics, he'll have to face the fact that self-organization happens.

By the way, Kuroneko's post is also correct.




* I called it "phenomenological equation" because it does not give a method to determine all its terms from first principles.
If you know the details of the processes occurring in the control volume at a microscopic level, then you can work out the terms.

** Ironically, googling the name Prigogine, brought me this: Thermodynamics of Natural Selection (PDF)
Abstract
It is shown that biological-natural-selection-like behavior can occur, as a general type of time evolution, in a statistical system where detailed balance is violated owing to the presence of metastable energy states. A model of a non-equilibrium phase transition corresponding to the spontaneous origin of self-reproduction in the system is suggested. After a phase transition, the system passes from one quasistationary distribution of self-reproducing subsystems to another, with an increase in the total organization, as long as the growth of the energy flow through the system or a reduction of energy dissipation in the system is possible. The entropy production is calculated for this process in terms of ldquoselective valuesrdquo of Eigen's theory for self-organization in autocatalytic systems. Correspondence of the extremal principle of Eigen's theory with the criterion of evolution in Prigogine's thermodynamics is established.

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Post by Wyrm »

To summarize Kuroneko's and Il Saggiatore's posts, the creationtard's statement "So evolutionists are dishonest when they say the Second Law of Thermodynamics does not apply to open systems!" is a straight-out lie.

It's also a completely transparent one, because imagine if it were true that the second law applies to open systems — nothing could grow complex. Nothing could grow. Life itself would be impossible.

"Ah, that proves that God is at work!" says the creationtard. Only it doesn't. It also means that cars (man's creation) would run down and could never be refueled. It also means that cars couldn't even be constructed. Nothing of man could be created. Yet it does. Point, set, and match.
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Post by wautd »

I havn't replied him yet but this:
Creationists recognize that energy alone does not allow systems to decrease in entropy while at the same time moving away from local equilibrium.
is bullshit too right?


Wyrm wrote: because imagine if it were true that the second law applies to open systems — nothing could grow complex. Nothing could grow. Life itself would be impossible.
Oh but I already tried to explain that by giving the growth of an embryo as example. But he then simply handwaved
There are no problems for an embryo to grow into a full grown baby because there exists all the templates, instructions, information, mechanisms, nanomachines etc which utilize energy that enables the embryo to grow into a baby.
:roll:

My favorite however is that after he said that evolution doesn't happen is this gem:
For example, microevolution is evidence of design.
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Post by Surlethe »

wautd wrote:I havn't replied him yet but this:
Creationists recognize that energy alone does not allow systems to decrease in entropy while at the same time moving away from local equilibrium.
is bullshit too right?
Yes. First, don't let him get away with just claiming it; force him to back it up from a thermodynamics textbook. Second, a heat engine is something that does just that (if I understand correctly).
Wyrm wrote:because imagine if it were true that the second law applies to open systems — nothing could grow complex. Nothing could grow. Life itself would be impossible.
Oh but I already tried to explain that by giving the growth of an embryo as example. But he then simply handwaved
There are no problems for an embryo to grow into a full grown baby because there exists all the templates, instructions, information, mechanisms, nanomachines etc which utilize energy that enables the embryo to grow into a baby.
:roll:
... nanomachines? There are nanomachines in babies?! :lol: Even with the information, templates, instruction, etc., he still has an open system decreasing in entropy. This handwaving is nothing but bar-raising.
My favorite however is that after he said that evolution doesn't happen is this gem:
For example, microevolution is evidence of design.
:lol: I'll be he doesn't even know what microevolution is.
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wautd
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Post by wautd »

Anyways, this will be my reply. Correct me if I'm wrong or forgot something
“You are the one that stated that the Second Law of Thermodynamics does not apply to open systems! I showed you the equation where it does apply! And you talk about opening physics books when you don't even understand the physics. “
Am I now? How is posting a (correct) entropy balance equation which indeed applies to an open system makes you jump to conclusion that it applies to the second law, which is about the rate of entropy production due to irreversible transformations in the control volume (sigma_cv) only?
If you actually understood the equation you copied, you would realize that this open system can reduce its entropy, that is, dScv/dt can be negative as long as Sum(me*se) is large enough or Sum(Qj/Tj) is negative. This is one of the reasons why an open system out of equilibrium can show self-organization... such as life.
So you shot yourself in the foot (again) because that equation exactly refutes the traditional creationist argument that the second law of thermodynamics would not allow the development of life.

So when you claim to be an educated person, do you actually mean that you skim creationist websites to copy/paste your strawman arguments? And when you say you work in engineering, that you work in a garage?
“Evolutionists have failed to explain the origin and development of life.”
Why would they? If you knew what you were talking about you would know evolution doesn’t make any claim about the origin of life. About the creation of life itself I'm agnostic in the way that the first life on earth could either have happened trough abiogenesis (what you seem to confuse with evolution) or by an intelligence (it doesn’t seem that science is that far off in doing that themselves anyway). However, life has evolved since has started. That's as much as a fact as the fact that gravity will make things fall down.
“They have failed to show how new biologic systems are able to develop through mutation and selection.”
Appeal to ignorance. The theory of evolution did provide such predictions. Two examples are:

* Genetic information must be transmitted in a molecular way that will be almost exact but permit slight changes. Indeed, since this prediction was made, biologists have discovered the existence of DNA, which has a mutation rate of roughly 10-9 per nucleotide per cell division; this provides just such a mechanism.[24]

* Some DNA sequences are shared by very different organisms. It has been predicted by the theory of evolution that the differences in such DNA sequences between two organisms should roughly resemble both the biological difference between them according to their anatomy and the time that had passed since these two organisms have separated in the course of evolution, as seen in fossil evidence. The rate of accumulating such changes should be low for some sequences, which code for critical RNA or proteins, and high for others - that code for less critical RNA or proteins; but for every specific sequence, the rate of change should be roughly constant through evolution. These results have indeed been found experimentally. Two examples are DNA sequences coding for rRNA which is highly conserved, and DNA sequences coding for fibrinopeptides (amino acid chains which are discarded during the formation of fibrin), which are highly non-conserved.

“but I think that much of the evidence can be explained by the Creationists model.”
Oh but I agree. In fact, you can explain the origin of life by using any of the hundreds creation myths that are in existence. However, it’s something else to prove a specific creation myth.
“For example, microevolution is evidence of design”
First you deny evolution happening and now you say that evolution is evidence of design. Do you even know what microevolution is?
“We can use science to show that the world wide flood occurred”
Apart from the fact that there isn’t enough water, nor any geological evidence, or that the kinetic energy alone would turned the earth in molten rock, that the world population couldn’t possibly recover that fast, that all plants and fish would have died out, that the ancient Egyptians failed to notice such flood, etc…
“We can use science to examine the age of the earth“
Well, the old-earth creationists anyway
“For example, Creationists recognize that energy alone does not allow systems to decrease in entropy while at the same time moving away from local equilibrium.”
Thank you for showing that creationists use natural laws that are different to that of what is used by the science. Second, a heat engine is something that does just that.
“The logic of some in science is not reasonable: "God is outside of our physical world; scientifically we cannot prove God; therefore, discussions of God are unscientific".
Since God can’t be seen or observed, nor tested or measured in any way, it’s unnecessary to include God in science. Science relies on empirical evidence. God is not a factor when you’re making calculations in say, building a bridge.
“What we can say about God is that we scientifically don't know whether he exists.”
Indeed
“So to be consistent scientifically, we should conduct science as an agnostic”
Sure. God may or not may exist. But that doesn’t change the fact that evolution occurs.
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Post by Vehrec »

Saying 'God Made the World' simply sets us back a step. What then made God? Do not accept people telling you you cannot understand God-after all, Adam and Eve ate from the tree of knowledge of Good and Evil and became so full of understanding that god had to throw them out lest they become a danger. Clearly, we are capable of the same level of understanding of the world as a Bronze-age deity. Therefore, if God is capable of understanding where He came from, we can understand this. This argument may need work, but I defend it's general principal-if God made everything, what then made God? Aren't we getting into an infinite regression? Isn't that a mess we would want to avoid?

To avoid a messy worldview, embrace change and materialism. Practice critical thinking and start using science.
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Post by SpacedTeddyBear »

Hey wautd, are you "From Belgium"? I believe I've stumbled onto the exchange you guys have been having and he has a bit to say about your last argument. I might toss myself into the fray, so here is my response to some of the stuff he's come up with:
Hardly, you don't get the decrease in entropy that is relevant to the origin of life or the development of new biologic systems without a mechanism that constrains the processes enabling them to occur.
It's called the Sun.
For example, a rock on a mountain will naturally tend to slide down the hill over time. In order to utilize the entropy rate equation to realize a entropy decreasing process (moving the rock up hill), you need constrained boundary conditions that utilize energy flow, which constitutes the thermodynamic mechanism.
Sure, lets constrain our boundary to include an area of space that include the sun.
In our rock example, a truck powered by an engine can be used to carry the rock up the hill. Applying the entropy rate equation to the system, we would realized that the net effect on the environment would be an entropy increase although the effect on the rock would be a decrease in entropy. But the ability to decrease entropy is limited by the functionality of the thermodynamic mechanism. For example, an engine by itself would not be able to move the rock up the hill. You would need power trains, gears, wheels, etc to enable the machine to work -- including an intelligent operator. Engineers are in the business of often developing entropy decreasing mechanisms. It takes work; it takes thought and intelligence; it takes other machines to develop these thermodynamic mechanisms. There is nothing natural about it!
What kind of an engineer would mistake spontaneous chemical reactions with self assembly of mechanical parts? Oh wait, they don't because engineers from accredited universities are educated enough to know better. Here's an idea, go and pick up a copy of any university level chemistry book ( The one by Brown, Lemay, and Burston is pretty good) before you go on ignorantly assuming mechanical parts like diodes, gears, and etc. can be thrown together to react like chemicals can.
Evolution teaches that a multitude of highly improbable states occur on the genome, consecutively leading to decreases in entropy which is in violation of the Second Law.
Wrong. Evolution teaches that random mutations that produces certain traits that favor an organisms survival in its native environment, will be passed onto later generations where it will result in these later generations to become the predominate organism. While you're at it, pick up a biology book.
The multitude of very precise mutations are required to enable the development of new systems, which are too improbable to be explained naturally: the Second Law of Thermodynamics holds true because the most probable states occur rather than the highly improbable states, which is required of evolution.
Precise mutations are required for precise physical features. Since we are talking about an arbitrary system, the number of mutations that can occur to develop new biological systems over billions of years is almost infinite. Life is billions of times more complex then our simple machines as you stated earlier, than there are obviously macrostates in a system that has the same multiplicity that is required for life. So yes the 2nd law does hold true since there are are billions of macrostates that are probable to support life.
To save space I will not go into all the details but I will ask this one simple question. Where on the genome is all the information allowing this structure to form? Is it one location or is it spread out over a multitude of locations over the genome, which stretches from the earth to the moon? There are the tear ducts, veins, special cells (rods and cones), and brain that has to process the information. And we need to remember that the genome must record the precise shapes of the parts. It is safe to say that there are over 100 parts plus all the information that specifies the shape and location of the parts. The point is that the information is large and at very specific locations. Not any mutations will bring about this system.
Not any mutations, but many. You see, that's where the billions of years of Earths existence comes in. And again you wrongly assume that the "design" of an eye must be very precise in order for it to function. Here's a little heads up for you: There A LOT of different kinds of eyes out there of varying complexities.
Now in the crap shoot game of evolution, how does it all come together? Evolutionists only speculate on this and invent stories to explain it.
Invent stories? Ha! This is coming from a person who supports an assertion that some arbitrary magical sky pixie came about and created life on this planet and wants it to be taught as a science.



OK I have to sleep now. I think I'm getting a bit sloppy. Comments? Criticisms?
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